Abstract:

Superconductivity often emerges as a dome around a quantum critical point (QCP) where long- range order is suppressed to zero temperature, e.g., in high-temperature superconductors. However, the presence of a putative charge-density-wave (CDW) QCP and its impact on emerging superconductivity received increased scientific attention only after the discovery of CDW order in copper oxides. By now, it is known that various metallic transition-metal dichalcogenides feature emergent superconductivity when CDW order is suppressed, e.g., by pressure or intercalation and researchers are trying to understand the relevance of a CDW QCP for superconductivity in these systems.

Here, I will present our study of the canonical CDW compound 2H-TaSe2. We used inelastic x-ray scattering (IXS) and x-ray diffraction (XRD) at ambient and high pressures up to 25 GPa to determine the CDW phase diagram and study its lattice dynamical properties. Our experimental results are complemented by ab-initio lattice dynamical calculations based on density-functional perturbation theory. Results at ambient pressure provide first evidence for a full phonon softening at the CDW transition in 2H-TaSe2 and reveal a novel precursor region above the CDW transition temperature TCDW, which is characterized by an overdamped phonon mode without long range order. Our high-pressure XRD defines the critical pressure pc ≈ 20 GPa at which CDW order is fully suppressed. IXS identifies the presence of a CDW soft phonon mode at pc which is strong evidence for a continuous nature of the CDW transition near zero temperature, and, thus, a CDW QCP. Calculations show that electron-phonon coupling in 2H-TaSe2 is mostly carried by the CDW soft phonon mode and can rationalize the reported superconducting transition temperatures at high pressures. 

Location:
437 / C010

Virtual Link:
Microsoft Teams Need help?
Join the meeting now
Meeting ID: 288 164 043 627
Passcode: USyj2j