Reappearing Superconductivity Surprises Scientists

FEBRUARY 24, 2012

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A view of the structural unit of high-temperature cuprate- and iron selenide-based superconductors. Figure courtesy of Xiao-Jia Chen.

Researchers working at two synchrotron light sources have demonstrated unexpected superconductivity in a type of compounds called iron selenium chalcogenides. Their work, based on studies carried out at beamline 16-BM-D of the High Pressure Collaborative Access Team at the U.S. Department of Energy Office of Science’s Advanced Photon Source, Argonne National Laboratory, and beamline BL15U at Shanghai Synchrotron Radiation Facilities, was published online by Nature on February 22, 2012.

Superconductivity is a rare physical state in which matter is able to conduct electricity—maintain a flow of electrons—without any resistance. This phenomenon can only be found in certain materials at low temperatures, or can be induced under chemical and high external pressure conditions. Research to create superconductors at higher temperatures has been ongoing for two decades with the promise of significant impact on electrical transmission.

A superconducting substance’s electrical resistance disappears at a critical transition temperature, TC. The early conventional superconductors had to be cooled to extremely low temperatures—below TC—in order for electricity to flow freely. Then in the 1980s, scientists discovered a class of relatively high-temperature superconductors. Researchers have continued to study this phenomenon and look for it in an array of materials. It has been established that superconductivity can be affected by a substance’s crystallographic structure, electronic charge, or the orbit of its electrons.

Recently, scientists have discovered superconductivity in iron-based selenium chalcogenides, compounds that combine an element from group 16 on the periodic table (referring sulfur, selenium, tellurium) with another element, in this case iron.

It was known that under pressure, iron selenides (a chemical compound containing selenium) become superconducters between -406 and -402 degrees Fahrenheit (30 Kelvin-32 Kelvin). But the research team, with members from the Chinese Academy of Sciences, the Carnegie Institution of Washington, the South China University of Technology, the National Institute of Standards and Technology, and Zhejiang University discovered that a second wave of superconductivity can be observed at higher pressures.

Working on an iron-based selenide the team observed a transition temperature that started at -400 degrees Fahrenheit (33 Kelvin) under about 16,000 times normal atmospheric pressure (1.6 gigapascals, or GPa) and shifts to lower temperatures as the pressure increases, until it vanishes at about 89,000 times atmospheric pressure (9 GPa). But then superconducting reappears at pressures with a transition temperature of about -373 degrees Fahrenheit at around 122,000 times atmospheric pressure (12.4 GPa).

“These observations highlight the search of high-temperature superconductivity in complex structural and magnetic materials,” Carnegie’s Xiao-Jia Chen said.

The researchers confirmed their results with a variety of magnetic and electrical resistance measurements. They were also able to find reemerging superconductivity in another type of iron-based selenium chalcogenide, under very similar conditions.

They observed that the basic structure of these compounds was not changed under the extreme pressure and thus further research is needed to determine what is happening on a closer structural level.

“Our work will likely stimulate a great deal of future study, both experimental and theoretical,” Chen said, “in order to clarify what causes this reemergence of superconductivity.”

See: Liling Sun1, Xiao-Jia Chen2,3, Jing Guo1, Peiwen Gao1, Qing-Zhen Huang4, Hangdong Wang5, Minghu Fang5, Xiaolong Chen1, Genfu Chen1, Qi Wu1, Chao Zhang1, Dachun Gu1, Xiaoli Dong1, Lin Wang2, Ke Yang1, Aiguo Li1, Xi Dai1, Ho-kwang Mao2*, and Zhongxian Zhao1**, “Re-emerging superconductivity at 48 kelvin in iron Chalcogenides,” Nature, published online February 22, 2012. DOI:10.1038/nature10813

Author affiliations: 1Chinese Academy of Sciences, 2Carnegie Institution of Washington, 3South China University of Technology, 4National Institute of Standards and Technology, 5Zhejiang University

Correspondence: **, *

Use of the Advanced Photon Source at Argonne National Laboratory was supported by the U.S. Department of Energy Office (DOE) of Science under Contract No. DE-AC02-06CH11357.

The work in the U.S.A. was supported as part of the EFree, an Energy Frontier Research Center funded by the DOE Office of Science. The High Pressure Collaborative Access Team is supported by the Carnegie Institution of Washington, the Carnegie/DOE Alliance Center, the University of Nevada Las Vegas and Lawrence Livermore National Laboratory through funding from the DOE-National Nuclear Security Administration, the DOE, and the National Science Foundation.

The original Carnegie Institution for Science press release can be found here.

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